大试管回流消解-等离子体发射光谱／质谱法测定植物样品中多元素   总被引：2，自引：1，他引：2  

马生凤温宏利  巩爱华孙德忠 《岩矿测试》2007,26(3):183-187

采用大试管和红外加热的多孔控温消解炉的简单装置消解植物样品，电感耦合等离子体发射光谱／质谱法测定其中的主量和痕量元素，对消解温度、消解时间、消解溶剂、样品取样量等条件进行考察。用植物国家一级标准物质进行前处理及测定，验证方法的可行性，测定值与标准值基本吻合。方法不仅能同时测定B、Ba、Ca、Cd、Cu、K、Mg、Mn、Na、Ni、P、S、Zn、CoSr、Pb、Cr等元素，还适用于Hg、As挥发性元素的消解测定。方法的精密度（RSD，n=10）≤10％。  相似文献   

辽河流域人发中重金属元素分布特征   总被引：4，自引：0，他引：4  

乌爱军  杨晓波马力于成广  王丹阳 《岩矿测试》2007,26(4):305-308

对辽河流域人发中重金属元素含量分布、分配规律研究结果表明：重金属元素尤其是铅、镉、汞、砷、铬元素，分布规律有很大相同之处，高含量数据点均围绕沈阳、锦州等重工业城市及阜新、柴河铅矿及其下游等地区分布，且城市居民平均含量明显高于乡村居民平均水平。通过进一步对典型污染区的研究发现：人发分布特征与背景环境有很大相关性，即土壤、浅层地下水、作物中重金属含量高的地区，人发中重金属含量亦较高。  相似文献   

重金属离子在胡敏酸-高岭石复合体上的吸附   总被引：6，自引：0，他引：6  

何为红李福春  吴志强代静玉 刘本定 《岩石矿物学杂志》2007,26(4):359-365

本文研究了胡敏酸存在下高岭石对重金属离子的吸附行为。实验结果表明:①胡敏酸和Cu2 溶液按先后顺序或同时加入高岭石中反应,在Cu2 平衡浓度<10mg/L时,3种加入顺序对Cu2 的吸附量基本相同,当Cu2 平衡浓度>10mg/L时,(K Cu) HA和(K Cu HA)两种加入顺序对Cu2 的吸附量比(K HA) Cu的略大。②在pH=5时,胡敏酸-高岭石复合体对Cu2 的吸附量明显大于纯高岭石。这是由于胡敏酸含有大量的羧基和酚羟基等活性基团,吸附在高岭石上的胡敏酸增加了其表面吸附位,在复合体表面形成了S—HA—Cu三元配合物,且Cu2 的吸附量与复合体中胡敏酸的含量在一定范围内成正相关;③溶液pH值在4～7之间变化可调控复合体对Cu2 的吸附机制。④在Cu2 和Cd2 共存时,随着金属离子初始浓度的增大,Cu2 的吸附量呈直线上升,而Cd2 的吸附量增加缓慢,表明复合体对Cu2 的吸附能力比对Cd2 强。  相似文献   

Determination of Total Organic Carbon Content and δ¹³C in Carbonate-Rich Detrital Sediments     

Valier Galy  Julien Bouchez  Christian France-Lanord 《Geostandards and Geoanalytical Research》2007,31(3):199-207

The determination of total organic carbon content and composition in detrital sediments requires careful removal of their carbonate minerals. In detrital sediments containing large amounts of carbonates, including dolomite, this can only be achieved by liquid acid leaching that may solubilise a significant proportion of the organic carbon. For a set of detrital sediments from the Himalayan system and the Amazon River as well as five geological reference materials, we determined the proportion of organic carbon (C_org) solubilised during acid leaching. This proportion is significant for all analysed sediments and generally tends to increase with the organic carbon content. Compared to other types of sediments analysed, clay fractions extracted from river sediments and bed sediments with very low organic carbon content have high and low proportions of acid soluble C_org respectively. In Himalayan and Amazon river sediments, the proportion of C_org solubilised during acid leaching was relatively constant with average values of 14 and 19 % respectively. Thus, it is possible to correct the C_org content for the dissolved organic carbon content measured after decarbonation. Data presented here show that C_org dissolved during liquid acid leaching must be taken into account. After careful calibration, the method presented here should, therefore, be applied to any carbonate-rich detrital sediment.  相似文献   

Heavy clastic minerals from the Far East island-arc complexes     

A. I. Malinovsky  P. V. Markevich 《Russian Journal of Pacific Geology》2007,1(1):71-81

The results of the study of heavy clastic minerals from the Cretaceous-Paleogene terrigenous complexes of Sikhote-Alin and Kamchatka, as well as from the Cenozoic sediments of the deepwater Vanuatu Trench, are summarized. The data obtained have been interpreted on the basis of their comparison with heavy mineral assemblages of recent sediments deposited in known geodynamic settings. It is shown that the heavy clastic minerals of sedimentary rocks, their relative quantities, and chemical compositions may serve as reliable indicators of different island-arc settings and magmatic processes; these indicators may also be used for identification of such settings in paleobasins of orogenic regions.  相似文献   

Geochemical Evidence for Slab Melting in the Trans-Mexican Volcanic Belt   总被引：3，自引：0，他引：3  

Gomez-Tuena  Arturo; Langmuir  Charles H.; Goldstein  Steven L.; Straub  Susanne M.; Ortega-Gutierrez  Fernando 《Journal of Petrology》2007,48(3):537-562

Geochemical studies of Plio-Quaternary volcanic rocks from theValle de Bravo–Zitácuaro volcanic field (VBZ) incentral Mexico indicate that slab melting plays a key role inthe petrogenesis of the Trans-Mexican Volcanic Belt. Rocks fromthe VBZ are typical arc-related high-Mg andesites, but two differentrock suites with distinct trace element patterns and isotopiccompositions erupted concurrently in the area, with a traceelement character that is also distinct from that of other Mexicanvolcanoes. The geochemical differences between the VBZ suitescannot be explained by simple crystal fractionation and/or crustalassimilation of a common primitive magma, but can be reconciledby the participation of different proportions of melts derivedfrom the subducted basalt and sediments interacting with themantle wedge. Sr/Y and Sr/Pb ratios of the VBZ rocks correlateinversely with Pb and Sr isotopic compositions, indicating thatthe Sr and Pb budgets are strongly controlled by melt additionsfrom the subducted slab. In contrast, an inverse correlationbetween Pb(Th)/Nd and ¹⁴³Nd/¹⁴⁴Nd ratios, which extend to lowerisotopic values than those for Pacific mid-ocean ridge basalts,indicates the participation of an enriched mantle wedge thatis similar to the source of Mexican intraplate basalts. In addition,a systematic decrease in middle and heavy rare earth concentrationsand Nb/Ta ratios with increasing SiO₂ contents in the VBZ rocksis best explained if these elements are mobilized to some extentin the subduction flux, and suggests that slab partial fusionoccurred under garnet amphibolite-facies conditions. KEY WORDS: arcs; mantle; Mexico; sediment melting; slab melting  相似文献   

陆相沉积的天文地层研究方法简介——以井下地层为例   总被引：2，自引：5，他引：2  

XU Dao-yi )  ZHANG Hai-feng )  HAN Yan-ben )  YIN Zhi-qiang )  LI Bao-li )  YAO Yi-min ) ) Institute of Geology  China Earthquake Administration  Beijing    ) Geological Scientific Research Institute of Shengli Oilfield Company  SINOPEC  Dongying    ) National Astronomical Observatories  Chinese Academy of Sciences  Beijing 《地层学杂志》2007,(Z2)

通过对我国大陆三十余口井的测井资料研究成果,归纳出对陆相地层进行天文地层研究的方法。介绍了所用的新的天文周期理论值、测井资料的选取及预处理方法,重点说明谱分析的数据点数的选定、不同参数(自然伽玛、自然电位和岩屑)的测井资料谱分析结果的对比,以实例说明如何选定主要优势旋回和AR值,以及FIR数字滤波器的基本性质和数字滤波结果,小波分析的特点和通过小波图进行调频的方法,并介绍了地层单位的延续时间计算和年龄确定方法。  相似文献   

一次大暴雨过程中低空急流演变与强降水的关系   总被引：18，自引：1，他引：18       下载免费PDF全文

金巍  曲岩  姚秀萍  黄素文 《气象》2007,33(12):31-38

利用营口新一代天气雷达提供的每6分钟一次的风廓线资料,详细分析了2006年6月29日辽宁省西部大暴雨过程中强降雨时段的低空风场结构。得出:此次强降水天气的发生与低空急流的迅速加强和向下扩展相对应,短时大暴雨发生前低空西南急流提前2小时左右开始有动量快速下传,当20m.s-1的急流中心下传到≤1km超低空,1.2～2.1km低空出现24m.s-1东南急流,有利于产生短时大暴雨;说明低空脉动及向地面扩展程度与短时强降水之间关系密切。低空急流到达测站上空不一定立即产生强降水,有时会滞后1～2个小时,强降水或强烈天气的发生都存在着一定的动量下传,引起低空扰动加强,同时低空急流的强度和伸展高度,以及动量下传的能量大小,都直接制约着强降水的强弱。低空急流指数增大的程度和降水量的强度呈正比关系,低空急流指数不仅可以说明低空急流的脉动以及向地面扩展程度与中小尺度的强降水存在密切的关系,同时对强降水的出现以及雨强的大小有一定的预示作用。  相似文献   

STUDY ON THE CAUSE OF HEAVY RAIN 200506 （HR200506） IN GUANGDONG     

郑彬  林爱兰  袁金南  谷德军  李春晖  梁建茵 《热带气象学报(英文版)》2007,13(2):145-148

A continuous heavy rain visited Guangdong province during June 18-25, 2005 (named Heavy Rain 200506, HR200506) and had resulted in enormous economic loss. The ageostropic Q vectors, θse,meridional circulation, computed from the NCEP reanalysis, and TBB are used to study the rainfall processes. The results indicated that a convective system moved northwards from the South China Sea (SCS)and stayed in Guangdong for several days, which was a direct cause of HR200506. The process is a result of the activity of the South China Sea summer monsoon. There were two rainbands of HR200506 in Guangdong. One laid in the north of Guangdong that produced frontal rainfall; another situated on the south of Guangdong which produced monsoon rainfall.  相似文献   

广西强降水强对流天气专业预报服务系统     

李勇  钟利华 《广西气象》2007,28(4):49-51

分析了当前专业预报服务的现状,根据需要建立了一套完善的强降水、强对流天气动态监测、分析和预报服务系统。该系统具有对气象信息采集、加工、分发、传输等自动化的功能,实现了对强降水、强对流天气、台风的实时监测和及时发布。  相似文献